|
gptkbp:instanceOf
|
gptkb:chemical_compound
|
|
gptkbp:application
|
synthesis of natural products
synthesis of pharmaceuticals
synthesis of polymers
|
|
gptkbp:catalyzes
|
palladium complex
nickel complex
|
|
gptkbp:discoveredIndependentlyBy
|
gptkb:Jean-Pierre_Corriu
gptkb:Makoto_Kumada
|
|
gptkbp:field
|
organic chemistry
|
|
gptkbp:firstReported
|
1972
|
|
https://www.w3.org/2000/01/rdf-schema#label
|
Kumada–Corriu coupling
|
|
gptkbp:involves
|
aryl halide
organomagnesium compound
alkenyl halide
|
|
gptkbp:mechanismOfAction
|
oxidative addition
reductive elimination
transmetalation
|
|
gptkbp:namedAfter
|
gptkb:Jean-Pierre_Corriu
gptkb:Makoto_Kumada
|
|
gptkbp:otherName
|
gptkb:Kumada_coupling
Kumada cross-coupling
|
|
gptkbp:product
|
biaryl compound
alkenyl-aryl compound
|
|
gptkbp:reactionClass
|
transition metal-catalyzed coupling
|
|
gptkbp:relatedTo
|
gptkb:Negishi_coupling
gptkb:Heck_reaction
gptkb:Suzuki_coupling
gptkb:Stille_coupling
|
|
gptkbp:substrate
|
gptkb:Grignard_reagent
aryl bromide
aryl chloride
aryl iodide
|
|
gptkbp:type
|
cross-coupling reaction
|
|
gptkbp:bfsParent
|
gptkb:Kumada_coupling
|
|
gptkbp:bfsLayer
|
7
|