Statements (31)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
|
| gptkbp:application |
pharmaceuticals
organic synthesis natural product synthesis |
| gptkbp:catalyzes |
nickel
palladium |
| gptkbp:field |
organometallic chemistry
synthetic chemistry |
| gptkbp:firstReported |
1977
|
| https://www.w3.org/2000/01/rdf-schema#label |
Negishi coupling
|
| gptkbp:involves |
organometallic compound
organohalide |
| gptkbp:mechanismOfAction |
oxidative addition
reductive elimination transmetalation |
| gptkbp:namedAfter |
gptkb:Ei-ichi_Negishi
|
| gptkbp:NobelPrizeYear |
gptkb:Ei-ichi_Negishi
2010 |
| gptkbp:product |
carbon-carbon bond
|
| gptkbp:reactant |
aryl halide
organozinc compound vinyl halide |
| gptkbp:relatedTo |
gptkb:Heck_reaction
gptkb:Suzuki_coupling gptkb:Kumada_coupling gptkb:Stille_coupling |
| gptkbp:solvent |
gptkb:tetrahydrofuran
dimethylformamide |
| gptkbp:type |
cross-coupling reaction
|
| gptkbp:bfsParent |
gptkb:Ei-ichi_Negishi
|
| gptkbp:bfsLayer |
5
|