triphenylphosphine

GPTKB entity

Statements (49)
Predicate Object
gptkbp:instanceOf gptkb:chemical_compound
organophosphorus compound
gptkbp:appearance white crystalline solid
gptkbp:aroma faint, unpleasant
gptkbp:boilingPoint 377 °C (decomposes)
gptkbp:CASNumber 603-35-0
gptkbp:chemicalFormula C18H15P
gptkbp:component gptkb:phosphorus
carbon
hydrogen
gptkbp:density 1.19 g/cm³
gptkbp:discoveredIn late 19th century
gptkbp:EC_number 210-036-0
gptkbp:foundIn gptkb:Germany
gptkbp:GHSClassification exclamation mark
gptkbp:hasInChIKey gptkb:RZVAJINKPMORJF-UHFFFAOYSA-N
gptkbp:hasSMILES c1ccc(cc1)P(c2ccccc2)c3ccccc3
https://www.w3.org/2000/01/rdf-schema#label triphenylphosphine
gptkbp:IUPACName triphenylphosphane
gptkbp:meltingPoint 80-83 °C
gptkbp:molecularWeight 262.29 g/mol
gptkbp:PubChem_CID gptkb:CHEBI:30713
gptkb:CHEMBL1230992
6625
gptkbp:refractiveIndex 1.659
gptkbp:relatedTo gptkb:triphenylphosphine_oxide
gptkb:triphenylphosphite
gptkbp:riskFactor H315 (causes skin irritation)
H319 (causes serious eye irritation)
H335 (may cause respiratory irritation)
H302 (harmful if swallowed)
gptkbp:sensitivity air stable
light sensitive
gptkbp:solubility insoluble
gptkbp:solubilityInOrganicSolvents soluble
gptkbp:storage store in a cool, dry place
gptkbp:structure trigonal pyramidal geometry
gptkbp:synthesisType reaction of phosphorus trichloride with phenylmagnesium bromide
reaction of phosphorus trichloride with phenyl lithium
gptkbp:UNII 8KX6Y2PZ4P
gptkbp:uses gptkb:Wittig_reaction
gptkb:Mitsunobu_reaction
gptkb:Staudinger_reaction
reagent in organic synthesis
ligand in organometallic chemistry
gptkbp:bfsParent gptkb:Wilkinson's_catalyst
gptkb:Corey–Fuchs_reaction
gptkb:Corey–Nicolaou_macrolactonization
gptkbp:bfsLayer 6