|
gptkbp:instanceOf
|
gptkb:chemical_compound
gptkb:organophosphorus_compound
|
|
gptkbp:appearance
|
white crystalline solid
|
|
gptkbp:aroma
|
faint, unpleasant
|
|
gptkbp:boilingPoint
|
377 °C (decomposes)
|
|
gptkbp:CASNumber
|
603-35-0
|
|
gptkbp:chemicalFormula
|
C18H15P
|
|
gptkbp:component
|
gptkb:phosphorus
carbon
hydrogen
|
|
gptkbp:density
|
1.19 g/cm³
|
|
gptkbp:discoveredIn
|
late 19th century
|
|
gptkbp:EC_number
|
210-036-0
|
|
gptkbp:foundIn
|
gptkb:Germany
|
|
gptkbp:GHSClassification
|
exclamation mark
|
|
gptkbp:hasInChIKey
|
gptkb:RZVAJINKPMORJF-UHFFFAOYSA-N
|
|
gptkbp:hasSMILES
|
c1ccc(cc1)P(c2ccccc2)c3ccccc3
|
|
gptkbp:IUPACName
|
triphenylphosphane
|
|
gptkbp:meltingPoint
|
80-83 °C
|
|
gptkbp:molecularWeight
|
262.29 g/mol
|
|
gptkbp:PubChem_CID
|
gptkb:CHEBI:30713
gptkb:CHEMBL1230992
6625
|
|
gptkbp:refractiveIndex
|
1.659
|
|
gptkbp:relatedTo
|
gptkb:triphenylphosphine_oxide
gptkb:triphenylphosphite
|
|
gptkbp:riskFactor
|
H315 (causes skin irritation)
H319 (causes serious eye irritation)
H335 (may cause respiratory irritation)
H302 (harmful if swallowed)
|
|
gptkbp:sensitivity
|
air stable
light sensitive
|
|
gptkbp:solubility
|
insoluble
|
|
gptkbp:solubilityInOrganicSolvents
|
soluble
|
|
gptkbp:storage
|
store in a cool, dry place
|
|
gptkbp:structure
|
trigonal pyramidal geometry
|
|
gptkbp:synthesisType
|
reaction of phosphorus trichloride with phenylmagnesium bromide
reaction of phosphorus trichloride with phenyl lithium
|
|
gptkbp:UNII
|
8KX6Y2PZ4P
|
|
gptkbp:uses
|
gptkb:Wittig_reaction
gptkb:Mitsunobu_reaction
gptkb:Staudinger_reaction
reagent in organic synthesis
ligand in organometallic chemistry
|
|
gptkbp:bfsParent
|
gptkb:Wilkinson's_catalyst
gptkb:Corey–Fuchs_reaction
gptkb:Corey–Nicolaou_macrolactonization
|
|
gptkbp:bfsLayer
|
6
|
|
https://www.w3.org/2000/01/rdf-schema#label
|
triphenylphosphine
|