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gptkbp:instanceOf
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gptkb:chemical_compound
homogeneous catalyst
organometallic compound
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|
gptkbp:CASNumber
|
gptkb:14694-95-2
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gptkbp:category
|
hydrogenation catalysts
organophosphine complexes
rhodium complexes
transition metal complexes
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gptkbp:chemicalFormula
|
gptkb:RhCl(PPh3)3
|
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gptkbp:color
|
deep red
|
|
gptkbp:containsElement
|
gptkb:chlorine
gptkb:phosphorus
carbon
hydrogen
rhodium
|
|
gptkbp:discoveredBy
|
gptkb:Geoffrey_Wilkinson
|
|
gptkbp:firstReported
|
1965
|
|
https://www.w3.org/2000/01/rdf-schema#label
|
Wilkinson's catalyst
|
|
gptkbp:IUPACName
|
gptkb:chlorotris(triphenylphosphine)rhodium(I)
|
|
gptkbp:ligand
|
gptkb:triphenylphosphine
chloride
|
|
gptkbp:molecular_geometry
|
square planar
|
|
gptkbp:molecularWeight
|
925.22 g/mol
|
|
gptkbp:namedAfter
|
gptkb:Geoffrey_Wilkinson
|
|
gptkbp:oxidation_state_of_rhodium
|
+1
|
|
gptkbp:solubility
|
soluble in benzene
soluble in chlorinated solvents
soluble in toluene
|
|
gptkbp:used_in
|
homogeneous catalysis
|
|
gptkbp:usedFor
|
hydrogenation of alkenes
|
|
gptkbp:bfsParent
|
gptkb:Geoffrey_Wilkinson
gptkb:Sir_Geoffrey_Wilkinson
|
|
gptkbp:bfsLayer
|
5
|