Statements (20)
Predicate | Object |
---|---|
gptkbp:instanceOf |
gptkb:chemical_compound
|
gptkbp:application |
natural product synthesis
synthesis of allylic amines |
gptkbp:category |
organic chemistry
name reaction |
gptkbp:firstReported |
1974
|
https://www.w3.org/2000/01/rdf-schema#label |
Overman rearrangement
|
gptkbp:mechanismOfAction |
gptkb:[3,3]-sigmatropic_rearrangement
|
gptkbp:medium |
trichloroacetimidate
|
gptkbp:namedAfter |
gptkb:Larry_Overman
|
gptkbp:product |
allylic amine
allylic trichloroacetamide |
gptkbp:relatedTo |
gptkb:Cope_rearrangement
gptkb:Claisen_rearrangement |
gptkbp:substrate |
allylic alcohol
|
gptkbp:type |
rearrangement reaction
sigmatropic rearrangement |
gptkbp:bfsParent |
gptkb:Larry_Overman
gptkb:Larry_E._Overman |
gptkbp:bfsLayer |
6
|