[3,3]-sigmatropic rearrangement
GPTKB entity
Statements (18)
Predicate | Object |
---|---|
gptkbp:instanceOf |
gptkb:chemical_compound
|
gptkbp:bond_shift |
three atoms to three atoms
|
gptkbp:commonIn |
organic chemistry
|
gptkbp:example |
gptkb:Cope_rearrangement
gptkb:Claisen_rearrangement |
gptkbp:governedBy |
gptkb:Woodward–Hoffmann_rules
|
https://www.w3.org/2000/01/rdf-schema#label |
[3,3]-sigmatropic rearrangement
|
gptkbp:involves |
pericyclic reaction
concerted mechanism |
gptkbp:mechanismOfAction |
concerted
|
gptkbp:product |
isomer
|
gptkbp:requires |
heat
|
gptkbp:transitionState |
six-membered ring
|
gptkbp:type |
rearrangement reaction
sigmatropic rearrangement |
gptkbp:bfsParent |
gptkb:Ireland–Claisen_rearrangement
gptkb:Eschenmoser–Claisen_rearrangement |
gptkbp:bfsLayer |
6
|