Statements (23)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
|
| gptkbp:application |
synthesis of natural products
carbon–carbon bond formation |
| gptkbp:category |
gptkb:chemical_compound
rearrangement reaction |
| gptkbp:discoveredBy |
gptkb:Ludwig_Claisen
|
| gptkbp:discoveredIn |
1912
|
| https://www.w3.org/2000/01/rdf-schema#label |
Claisen rearrangement
|
| gptkbp:mechanismOfAction |
concerted
|
| gptkbp:namedAfter |
gptkb:Ludwig_Claisen
|
| gptkbp:notableFeature |
pericyclic reaction
stereospecific |
| gptkbp:product |
γ,δ-unsaturated carbonyl compound
|
| gptkbp:reactant |
allyl vinyl ether
|
| gptkbp:reactionCondition |
heat
|
| gptkbp:type |
gptkb:[3,3]-sigmatropic_rearrangement
|
| gptkbp:variant |
gptkb:Ireland–Claisen_rearrangement
gptkb:Eschenmoser–Claisen_rearrangement gptkb:Bellus–Claisen_rearrangement gptkb:Johnson–Claisen_rearrangement |
| gptkbp:bfsParent |
gptkb:Ireland–Claisen_rearrangement
gptkb:Eschenmoser–Claisen_rearrangement |
| gptkbp:bfsLayer |
6
|