Statements (22)
Predicate | Object |
---|---|
gptkbp:instanceOf |
gptkb:chemical_compound
|
gptkbp:application |
synthesis of complex molecules
|
gptkbp:category |
rearrangement reaction
named reaction pericyclic reaction |
gptkbp:designer |
true
|
gptkbp:discoveredBy |
gptkb:Arthur_C._Cope
|
gptkbp:discoveredIn |
1940
|
gptkbp:example |
3-methyl-1,5-hexadiene to 1,5-heptadiene
|
https://www.w3.org/2000/01/rdf-schema#label |
Cope rearrangement
|
gptkbp:namedAfter |
gptkb:Arthur_C._Cope
|
gptkbp:product |
isomeric 1,5-diene
|
gptkbp:reactionCondition |
thermal
|
gptkbp:reactionMechanism |
concerted
|
gptkbp:relatedTo |
gptkb:Claisen_rearrangement
|
gptkbp:substrate |
1,5-diene
|
gptkbp:transitionState |
six-membered ring
|
gptkbp:type |
gptkb:[3,3]-sigmatropic_rearrangement
pericyclic reaction sigmatropic rearrangement |
gptkbp:bfsParent |
gptkb:Arthur_C._Cope
|
gptkbp:bfsLayer |
6
|