Statements (24)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
|
| gptkbp:application |
synthesis of alkylbenzenes
|
| gptkbp:catalyzes |
gptkb:Lewis_acid
|
| gptkbp:commonCatalyst |
gptkb:aluminum_chloride
|
| gptkbp:firstDescribed |
1877
|
| https://www.w3.org/2000/01/rdf-schema#label |
Friedel–Crafts alkylation
|
| gptkbp:involves |
alkyl halide
aromatic compound |
| gptkbp:limitation |
overalkylation
rearrangement of carbocation intermediates |
| gptkbp:mechanismOfAction |
formation of carbocation intermediate
|
| gptkbp:namedAfter |
gptkb:James_Crafts
gptkb:Charles_Friedel |
| gptkbp:notRecommendedFor |
aromatic rings with strong electron-withdrawing groups
deactivated aromatic rings |
| gptkbp:product |
alkylated aromatic compound
|
| gptkbp:relatedTo |
gptkb:Friedel–Crafts_acylation
|
| gptkbp:sideReaction |
carbocation rearrangement
polyalkylation |
| gptkbp:solvent |
nonpolar solvent
|
| gptkbp:type |
gptkb:electrophilic_aromatic_substitution
|
| gptkbp:bfsParent |
gptkb:Friedel–Crafts_reaction
gptkb:Zelinsky_reaction |
| gptkbp:bfsLayer |
7
|