Ireland–Claisen rearrangement
GPTKB entity
Statements (21)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
|
| gptkbp:application |
natural product synthesis
stereoselective synthesis |
| gptkbp:basisFor |
gptkb:LDA
sodium hydride |
| gptkbp:category |
named reaction
pericyclic reaction |
| gptkbp:citation |
Ireland, R. E.; Mueller, R. H.; Willard, A. K. J. Am. Chem. Soc. 1976, 98, 2868-2877.
|
| gptkbp:discoveredIn |
1972
|
| https://www.w3.org/2000/01/rdf-schema#label |
Ireland–Claisen rearrangement
|
| gptkbp:involves |
allyl ester
ester enolate |
| gptkbp:mechanismOfAction |
gptkb:[3,3]-sigmatropic_rearrangement
|
| gptkbp:namedAfter |
gptkb:Robert_E._Ireland
|
| gptkbp:product |
γ,δ-unsaturated carboxylic acid
|
| gptkbp:relatedTo |
gptkb:Claisen_rearrangement
|
| gptkbp:solvent |
gptkb:THF
Ether |
| gptkbp:type |
rearrangement reaction
|
| gptkbp:bfsParent |
gptkb:Robert_E._Ireland
|
| gptkbp:bfsLayer |
5
|