Statements (23)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
|
| gptkbp:alsoKnownAs |
gptkb:pinacol–pinacolone_rearrangement
|
| gptkbp:application |
synthetic organic chemistry
|
| gptkbp:example |
conversion of pinacol to pinacolone
|
| gptkbp:firstReported |
gptkb:Friedel
1860 |
| https://www.w3.org/2000/01/rdf-schema#label |
pinacol rearrangement
|
| gptkbp:mechanismOfAction |
carbocation intermediate
|
| gptkbp:mechanismStep |
loss of water
carbocation rearrangement deprotonation protonation of diol |
| gptkbp:namedAfter |
gptkb:pinacolone
pinacol |
| gptkbp:product |
ketone
|
| gptkbp:relatedTo |
gptkb:Tiffeneau–Demjanov_rearrangement
gptkb:Wagner–Meerwein_rearrangement |
| gptkbp:requires |
gptkb:carboxylic_acid
|
| gptkbp:substrate |
vicinal diol
|
| gptkbp:type |
rearrangement reaction
acid-catalyzed reaction |
| gptkbp:bfsParent |
gptkb:Pinacol_coupling_reaction
|
| gptkbp:bfsLayer |
6
|