pinacol–pinacolone rearrangement
GPTKB entity
Statements (17)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
|
| gptkbp:category |
name reaction
carbon-carbon bond rearrangement |
| gptkbp:exampleSubstrate |
pinacol
|
| gptkbp:firstReported |
gptkb:Rudolph_Fittig
1860 |
| https://www.w3.org/2000/01/rdf-schema#label |
pinacol–pinacolone rearrangement
|
| gptkbp:involves |
vicinal diol
|
| gptkbp:launched |
gptkb:carboxylic_acid
|
| gptkbp:mechanismOfAction |
carbocation rearrangement
|
| gptkbp:otherName |
gptkb:pinacol_rearrangement
|
| gptkbp:produces |
ketone
|
| gptkbp:product |
gptkb:pinacolone
|
| gptkbp:type |
rearrangement reaction
|
| gptkbp:usedIn |
organic synthesis
|
| gptkbp:bfsParent |
gptkb:pinacol_rearrangement
|
| gptkbp:bfsLayer |
7
|