Tiffeneau–Demjanov rearrangement
GPTKB entity
Statements (20)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
|
| gptkbp:category |
name reaction
|
| gptkbp:field |
chemistry
|
| gptkbp:firstReported |
1903
|
| https://www.w3.org/2000/01/rdf-schema#label |
Tiffeneau–Demjanov rearrangement
|
| gptkbp:involves |
gptkb:nitrous_acid
amino alcohols |
| gptkbp:mechanismOfAction |
carbocation intermediate
|
| gptkbp:namedAfter |
Marc Tiffeneau
Nikolai Demjanov |
| gptkbp:produces |
enlarged ring ketones
|
| gptkbp:product |
cycloalkanone with larger ring
|
| gptkbp:reactionCondition |
acidic conditions
|
| gptkbp:relatedTo |
Demjanov rearrangement
ring expansion |
| gptkbp:substrate |
1-aminomethyl-cycloalkanols
|
| gptkbp:type |
rearrangement reaction
|
| gptkbp:usedIn |
organic synthesis
|
| gptkbp:bfsParent |
gptkb:pinacol_rearrangement
|
| gptkbp:bfsLayer |
7
|