Statements (50)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
organometallic compound |
| gptkbp:band |
covalent
ionic |
| gptkbp:category |
organomagnesium compounds
reagents for organic chemistry |
| gptkbp:containsElement |
carbon
magnesium halogen |
| gptkbp:cookingMethod |
reaction of alkyl or aryl halide with magnesium in dry ether
|
| gptkbp:decomposesIn |
presence of water
|
| gptkbp:discoveredBy |
gptkb:François_Auguste_Victor_Grignard
|
| gptkbp:example |
ethylmagnesium chloride
methylmagnesium bromide phenylmagnesium bromide |
| gptkbp:firstReported |
1900
|
| gptkbp:generalFormula |
RMgX
|
| https://www.w3.org/2000/01/rdf-schema#label |
Grignard reagents
|
| gptkbp:importantFor |
gptkb:Grignard_reaction
|
| gptkbp:namedAfter |
gptkb:François_Auguste_Victor_Grignard
|
| gptkbp:NobelPrizeYear |
gptkb:François_Auguste_Victor_Grignard
|
| gptkbp:riskFactor |
flammable
corrosive |
| gptkbp:sensitivity |
moisture
|
| gptkbp:solvent |
Ether
|
| gptkbp:state |
gptkb:government_agency
|
| gptkbp:storage |
under inert atmosphere
|
| gptkbp:type |
gptkb:water
carbonyl compounds nucleophilic |
| gptkbp:usedFor |
formation of carbon-carbon bonds
|
| gptkbp:usedIn |
organic synthesis
pharmaceutical synthesis preparation of primary alcohols preparation of secondary alcohols preparation of acids from esters preparation of alcohols from epoxides preparation of alkanes from alkyl halides preparation of amines from nitriles preparation of carboxylic acids from CO2 preparation of hydrocarbons preparation of tertiary alcohols synthesis of alcohols from aldehydes and ketones |
| gptkbp:usedToPrepare |
ketones
alcohols alkynes amines carboxylic acids |
| gptkbp:bfsParent |
gptkb:Victor_Grignard
|
| gptkbp:bfsLayer |
6
|