Statements (23)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
|
| gptkbp:application |
natural product synthesis
synthesis of complex molecules |
| gptkbp:bondChange |
pi bond rearrangement
sigma bond migration |
| gptkbp:discoveredIn |
1940
|
| gptkbp:example |
hexa-1,5-diene to 1,5-hexadiene isomerization
|
| gptkbp:field |
organic chemistry
|
| https://www.w3.org/2000/01/rdf-schema#label |
Cope reaction
|
| gptkbp:involves |
1,5-diene
|
| gptkbp:mechanismOfAction |
concerted
pericyclic |
| gptkbp:namedAfter |
gptkb:Arthur_C._Cope
|
| gptkbp:product |
isomeric 1,5-diene
|
| gptkbp:reactionClass |
gptkb:[3,3]-sigmatropic_rearrangement
|
| gptkbp:relatedTo |
gptkb:Claisen_rearrangement
oxy-Cope rearrangement |
| gptkbp:requires |
heat
|
| gptkbp:transitionState |
six-membered cyclic
|
| gptkbp:type |
rearrangement reaction
sigmatropic rearrangement |
| gptkbp:bfsParent |
gptkb:Cope
|
| gptkbp:bfsLayer |
6
|