Statements (18)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
|
| gptkbp:common_reagent |
gptkb:thiamine_(vitamin_B1)
cyanide ion N-heterocyclic carbene |
| gptkbp:contrastsWith |
normal reactivity of carbonyl compounds
|
| gptkbp:describes |
reversal of polarity of a functional group
|
| gptkbp:enables |
unusual bond formations
|
| gptkbp:field |
organic chemistry
|
| https://www.w3.org/2000/01/rdf-schema#label |
umpolung reaction
|
| gptkbp:introducedIn |
1979
|
| gptkbp:mechanismOfAction |
polarity inversion
|
| gptkbp:notableExample |
benzoin condensation
Stetter reaction |
| gptkbp:origin |
Dieter Seebach
|
| gptkbp:usedFor |
synthesizing 1,2-dicarbonyl compounds
synthesizing acyloin compounds |
| gptkbp:bfsParent |
gptkb:Corey–Seebach_reaction
|
| gptkbp:bfsLayer |
6
|