secondary kinetic isotope effect
GPTKB entity
Statements (18)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
kinetic isotope effect
|
| gptkbp:appliesTo |
organic reaction mechanisms
|
| gptkbp:canBe |
normal
inverse |
| gptkbp:commonIsotopes |
hydrogen
deuterium tritium |
| gptkbp:contrastsWith |
primary kinetic isotope effect
|
| gptkbp:dependsOn |
hybridization change
vibrational frequency change |
| gptkbp:describes |
change in reaction rate due to isotopic substitution at a site not directly involved in bond breaking/forming
|
| gptkbp:field |
chemistry
physical organic chemistry |
| https://www.w3.org/2000/01/rdf-schema#label |
secondary kinetic isotope effect
|
| gptkbp:measures |
ratio of rate constants for isotopically substituted and unsubstituted compounds
|
| gptkbp:usedFor |
mechanistic studies
|
| gptkbp:bfsParent |
gptkb:Kinetic_Isotope_Effect
|
| gptkbp:bfsLayer |
7
|