Statements (22)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
chemical phenomenon
|
| gptkbp:dependsOn |
bond vibrational frequencies
mass of isotopes |
| gptkbp:describes |
change in reaction rate due to isotopic substitution
|
| gptkbp:example |
hydrogen/deuterium substitution
|
| gptkbp:field |
chemistry
physical chemistry |
| gptkbp:firstDescribed |
gptkb:Harold_Urey
1930s |
| https://www.w3.org/2000/01/rdf-schema#label |
Kinetic Isotope Effect
|
| gptkbp:measures |
rate constant ratio (k_light/k_heavy)
|
| gptkbp:relatedTo |
isotopes
transition state theory reaction rate |
| gptkbp:symbol |
gptkb:KIE
|
| gptkbp:type |
gptkb:secondary_kinetic_isotope_effect
primary kinetic isotope effect |
| gptkbp:usedIn |
mechanistic studies
organic reaction mechanisms enzyme catalysis studies |
| gptkbp:bfsParent |
gptkb:KIE
|
| gptkbp:bfsLayer |
6
|