Sharpless asymmetric dihydroxylation
GPTKB entity
Statements (23)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
|
| gptkbp:application |
natural product synthesis
pharmaceutical synthesis |
| gptkbp:awarded |
gptkb:Nobel_Prize_in_Chemistry_2001
|
| gptkbp:catalyzes |
osmium tetroxide
|
| gptkbp:chiralLigandType |
cinchona alkaloid derivative
|
| gptkbp:co-catalyst |
chiral ligand
|
| gptkbp:developedBy |
gptkb:K._Barry_Sharpless
1980 |
| gptkbp:enables |
enantioselective synthesis
|
| https://www.w3.org/2000/01/rdf-schema#label |
Sharpless asymmetric dihydroxylation
|
| gptkbp:mechanismOfAction |
[3+2] cycloaddition
|
| gptkbp:namedAfter |
gptkb:K._Barry_Sharpless
|
| gptkbp:product |
vicinal diol
|
| gptkbp:reactant |
alkene
|
| gptkbp:relatedTo |
gptkb:Sharpless_epoxidation
asymmetric catalysis |
| gptkbp:solvent |
gptkb:water
gptkb:tert-butanol |
| gptkbp:type |
asymmetric synthesis
oxidation |
| gptkbp:bfsParent |
gptkb:K._Barry_Sharpless
|
| gptkbp:bfsLayer |
6
|