Statements (23)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
|
| gptkbp:application |
asymmetric synthesis
|
| gptkbp:awarded |
gptkb:Nobel_Prize_in_Physics
|
| gptkbp:catalyzes |
diethyl tartrate
titanium tetra(isopropoxide) |
| gptkbp:criteria |
high enantioselectivity
|
| gptkbp:discoveredBy |
gptkb:K._Barry_Sharpless
|
| gptkbp:discoveredIn |
1980
|
| gptkbp:enables |
enantioselective synthesis of epoxides
|
| gptkbp:field |
organic chemistry
|
| https://www.w3.org/2000/01/rdf-schema#label |
Sharpless epoxidation
|
| gptkbp:importantFor |
natural product synthesis
pharmaceutical synthesis |
| gptkbp:namedAfter |
gptkb:K._Barry_Sharpless
|
| gptkbp:oxidizer |
gptkb:tert-butyl_hydroperoxide
|
| gptkbp:product |
chiral epoxide
|
| gptkbp:relatedTo |
gptkb:Jacobsen_epoxidation
gptkb:Shi_epoxidation |
| gptkbp:substrate |
primary allylic alcohol
|
| gptkbp:type |
enantioselective epoxidation
|
| gptkbp:uses |
chiral catalyst
|
| gptkbp:bfsParent |
gptkb:K._Barry_Sharpless
|
| gptkbp:bfsLayer |
6
|