Lossen rearrangement

GPTKB entity

Statements (24)
Predicate Object
gptkbp:instanceOf gptkb:chemical_compound
gptkbp:activatedBy phosphorylation
acylation
sulfonylation
gptkbp:application synthesis of amines
synthesis of carbamates
synthesis of ureas
gptkbp:category name reaction in organic chemistry
gptkbp:firstReported 1872
gptkbp:followedBy migration to nitrogen atom
https://www.w3.org/2000/01/rdf-schema#label Lossen rearrangement
gptkbp:involves conversion of hydroxamic acids
gptkbp:mechanismOfAction loss of a leaving group
migration of an acyl group
gptkbp:medium isocyanate intermediate
gptkbp:namedAfter gptkb:Wilhelm_Lossen
gptkbp:produces isocyanates
gptkbp:relatedTo gptkb:Curtius_rearrangement
gptkb:Schmidt_reaction
gptkb:Hofmann_rearrangement
gptkbp:requires activation of hydroxamic acid
gptkbp:type rearrangement reaction
gptkbp:bfsParent gptkb:Hofmann_rearrangement
gptkbp:bfsLayer 6