Statements (22)
Predicate | Object |
---|---|
gptkbp:instanceOf |
gptkb:chemical_compound
|
gptkbp:alsoKnownAs |
gptkb:Curtius_reaction
|
gptkbp:application |
synthesis of amines
synthesis of carbamates synthesis of ureas |
gptkbp:category |
organic chemistry
named reactions |
gptkbp:firstReported |
1890
|
https://www.w3.org/2000/01/rdf-schema#label |
Curtius rearrangement
|
gptkbp:involves |
acyl azide
|
gptkbp:mechanismOfAction |
migration of R group from carbonyl carbon to nitrogen
|
gptkbp:medium |
isocyanate intermediate
|
gptkbp:namedAfter |
gptkb:Theodor_Curtius
|
gptkbp:produces |
nitrogen gas
isocyanate |
gptkbp:reactionCondition |
thermal decomposition
|
gptkbp:relatedTo |
gptkb:Lossen_rearrangement
gptkb:Schmidt_reaction gptkb:Hofmann_rearrangement |
gptkbp:type |
rearrangement reaction
|
gptkbp:bfsParent |
gptkb:Hofmann_rearrangement
|
gptkbp:bfsLayer |
6
|