Grubbs second-generation catalyst
GPTKB entity
Statements (38)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
cathedral
organometallic compound ruthenium complex |
| gptkbp:awards |
Nobel Prize in Chemistry 2005 (to Robert H. Grubbs for metathesis)
|
| gptkbp:CASNumber |
246047-72-3
|
| gptkbp:category |
homogeneous catalyst
transition metal complex |
| gptkbp:chemicalFormula |
C46H65Cl2N2PRu
|
| gptkbp:color |
deep purple
|
| gptkbp:containsElement |
gptkb:chlorine
gptkb:phosphorus carbon hydrogen nitrogen ruthenium |
| gptkbp:developedBy |
gptkb:Robert_H._Grubbs
|
| https://www.w3.org/2000/01/rdf-schema#label |
Grubbs second-generation catalyst
|
| gptkbp:introduced |
1999
|
| gptkbp:IUPACName |
benzylidene-bis(tricyclohexylphosphine)dichlororuthenium(II)-N-heterocyclic carbene
|
| gptkbp:ligand |
chloride
benzylidene N-heterocyclic carbene tricyclohexylphosphine |
| gptkbp:molecularWeight |
848.97 g/mol
|
| gptkbp:relatedTo |
gptkb:Grubbs_first-generation_catalyst
gptkb:Grubbs_third-generation_catalyst |
| gptkbp:replaces_ligand |
tricyclohexylphosphine
|
| gptkbp:solubility |
soluble in organic solvents
|
| gptkbp:stable |
air stable
moisture sensitive |
| gptkbp:structureType |
square planar geometry
|
| gptkbp:used_in |
organic synthesis
cross metathesis ring-closing metathesis ring-opening metathesis polymerization |
| gptkbp:usedFor |
olefin metathesis
|
| gptkbp:bfsParent |
gptkb:Grubbs_catalyst
|
| gptkbp:bfsLayer |
6
|