Grubbs first-generation catalyst
GPTKB entity
Statements (31)
Predicate | Object |
---|---|
gptkbp:instanceOf |
cathedral
organometallic compound ruthenium complex |
gptkbp:appearance |
purple solid
|
gptkbp:CASNumber |
172222-30-9
|
gptkbp:category |
homogeneous catalyst
transition metal complex |
gptkbp:chemicalFormula |
C48H72Cl2P2Ru
|
gptkbp:containsElement |
gptkb:chlorine
gptkb:phosphorus carbon hydrogen ruthenium |
gptkbp:discoveredBy |
gptkb:Robert_H._Grubbs
|
https://www.w3.org/2000/01/rdf-schema#label |
Grubbs first-generation catalyst
|
gptkbp:IUPACName |
(PCy3)2(Cl)2Ru=CHPh
|
gptkbp:ligand |
chloride
benzylidene tricyclohexylphosphine |
gptkbp:meltingPoint |
205 °C
|
gptkbp:molecularWeight |
848.04 g/mol
|
gptkbp:namedAfter |
gptkb:Robert_H._Grubbs
|
gptkbp:relatedTo |
gptkb:Grubbs_second-generation_catalyst
|
gptkbp:solubility |
soluble in benzene
soluble in toluene soluble in dichloromethane |
gptkbp:usedFor |
olefin metathesis
|
gptkbp:usedIn |
organic synthesis
|
gptkbp:bfsParent |
gptkb:Grubbs_second-generation_catalyst
gptkb:Grubbs_third-generation_catalyst |
gptkbp:bfsLayer |
7
|