Gilman reagents

GPTKB entity

Statements (23)
Predicate Object
gptkbp:instanceOf organocopper compound
gptkbp:category nucleophile
organometallic reagent
gptkbp:chemicalFormula R2CuLi
gptkbp:containsElement carbon
copper
hydrogen
lithium
gptkbp:cookingMethod reaction of copper(I) iodide with organolithium reagent
gptkbp:discoveredBy gptkb:Henry_Gilman
gptkbp:example lithium dimethylcuprate
lithium diphenylcuprate
https://www.w3.org/2000/01/rdf-schema#label Gilman reagents
gptkbp:isSolubleIn Ether
gptkbp:namedAfter gptkb:Henry_Gilman
gptkbp:stateAtRoomTemperature gptkb:stone
gptkbp:type alkyl halides
epoxides
acid chlorides
gptkbp:usedFor carbon-carbon bond formation
gptkbp:usedIn organic synthesis
gptkbp:bfsParent gptkb:Corey–Posner–Whitesides–House_reaction
gptkbp:bfsLayer 6