First Law of Thermodynamics

E314339

The First Law of Thermodynamics is the fundamental physical principle that states energy cannot be created or destroyed, only transformed or transferred, thereby conserving the total energy of an isolated system.

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Predicate Object
instanceOf conservation law
law of thermodynamics
physical law
alsoKnownAs First Law of Thermodynamics
surface form: energy conservation law in thermodynamics

First Law of Thermodynamics
surface form: law of conservation of energy
appliesTo closed systems
isolated systems
open systems
assumes energy is a state function
internal energy depends on the state of the system
constrains possible thermodynamic processes of a system
contrastsWith Second Law of Thermodynamics which introduces entropy and irreversibility
definesSymbol Q as heat added to the system
W as work done by the system
ΔU as change in internal energy of the system
expressedIn dU = δQ − δW in differential form
field physics
thermodynamics
historicalDevelopmentInvolves Hermann von Helmholtz
James Prescott Joule
Julius Robert von Mayer
Rudolf Clausius
historicalRoot principle of conservation of vis viva
implies no device can produce work without energy input
perpetual motion machines of the first kind are impossible
isFoundationFor analysis of heat engines
analysis of refrigerators and heat pumps
energy conservation in classical thermodynamics
thermodynamic energy balance equations
isPartOf four laws of thermodynamics
mathematicalForm ΔU = Q − W
precedes second law of thermodynamics
surface form: Second Law of Thermodynamics

third law of thermodynamics
surface form: Third Law of Thermodynamics
relatedTo Noether's theorem
surface form: Noether’s theorem

zeroth law of thermodynamics
surface form: Zeroth Law of Thermodynamics

conservation of mechanical energy
relatesConcept energy transfer
energy transformation
heat
internal energy
work
states energy can only be transformed from one form to another or transferred between systems
energy cannot be created or destroyed in an isolated system
the total energy of an isolated system remains constant
timePeriodOfFormulation 19th century
usedIn astrophysics
chemical thermodynamics
climate science
engineering thermodynamics
statistical mechanics

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Referenced by (4)

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On the Conservation of Force relatedTo First Law of Thermodynamics
third law of thermodynamics contrastsWith First Law of Thermodynamics
this entity surface form: first law of thermodynamics
First Law of Thermodynamics alsoKnownAs First Law of Thermodynamics
this entity surface form: law of conservation of energy
First Law of Thermodynamics alsoKnownAs First Law of Thermodynamics
this entity surface form: energy conservation law in thermodynamics