Statements (23)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
elimination reaction |
| gptkbp:carbocationIntermediate |
true
|
| gptkbp:commonIn |
weak base
|
| gptkbp:competitor |
SN1 reaction
|
| gptkbp:example |
dehydrohalogenation of alkyl halides
dehydration of alcohols |
| gptkbp:has_stereochemistry |
Zaitsev's rule favored
|
| https://www.w3.org/2000/01/rdf-schema#label |
E1 reaction
|
| gptkbp:leavingGroup |
good leaving group required
|
| gptkbp:mechanismOfAction |
two-step mechanism
|
| gptkbp:numberOfStages |
formation of carbocation
|
| gptkbp:product |
alkene
|
| gptkbp:rateDeterminingStep |
formation of carbocation
|
| gptkbp:rateLaw |
rate = k[substrate]
|
| gptkbp:rearrangementPossible |
true
|
| gptkbp:solvent |
polar protic solvent
|
| gptkbp:step |
loss of proton
|
| gptkbp:substratePreference |
tertiary > secondary > primary
|
| gptkbp:temperatureEffect |
favored by heat
|
| gptkbp:type |
unimolecular elimination
|
| gptkbp:bfsParent |
gptkb:SN1
|
| gptkbp:bfsLayer |
5
|