Statements (29)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
|
| gptkbp:advantage |
mild conditions
selectivity for alcohols |
| gptkbp:alsoKnownAs |
gptkb:Swern_oxidation
|
| gptkbp:byproduct |
carbon dioxide
carbon monoxide dimethyl sulfide |
| gptkbp:convertedTo |
secondary alcohol
primary alcohol |
| gptkbp:discoveredIn |
1972
|
| https://www.w3.org/2000/01/rdf-schema#label |
Corey–Suggs oxidation
|
| gptkbp:limitation |
dimethyl sulfide odor
|
| gptkbp:mechanismOfAction |
sulfonium ion intermediate
|
| gptkbp:namedAfter |
gptkb:Daniel_Swern
gptkb:E.J._Corey gptkb:Robert_Suggs |
| gptkbp:product |
aldehyde
ketone |
| gptkbp:publishedIn |
gptkb:Journal_of_Organic_Chemistry
|
| gptkbp:reactant |
gptkb:dimethyl_sulfoxide
oxalyl chloride triethylamine |
| gptkbp:relatedTo |
gptkb:Parikh–Doering_oxidation
gptkb:Pfitzner–Moffatt_oxidation |
| gptkbp:solvent |
dichloromethane
|
| gptkbp:temperature |
low temperature
|
| gptkbp:type |
oxidation
|
| gptkbp:bfsParent |
gptkb:Elias_J._Corey
|
| gptkbp:bfsLayer |
5
|