Statements (23)
Predicate | Object |
---|---|
gptkbp:instanceOf |
gptkb:chemical_compound
|
gptkbp:alternativeTo |
gptkb:Dess–Martin_oxidation
gptkb:Jones_oxidation PCC oxidation |
gptkbp:byproduct |
carbon dioxide
carbon monoxide dimethyl sulfide |
gptkbp:category |
alcohol oxidation reactions
|
gptkbp:convertedTo |
primary alcohols to aldehydes
secondary alcohols to ketones |
gptkbp:doesNotOxidize |
carboxylic acids
|
gptkbp:firstReported |
1978
|
https://www.w3.org/2000/01/rdf-schema#label |
Swern oxidation
|
gptkbp:mechanismOfAction |
sulfonium ion intermediate
|
gptkbp:namedAfter |
gptkb:Daniel_Swern
|
gptkbp:solvent |
dichloromethane
|
gptkbp:temperature |
low temperature
|
gptkbp:type |
oxidation
|
gptkbp:usesReagent |
gptkb:dimethyl_sulfoxide
oxalyl chloride triethylamine |
gptkbp:bfsParent |
gptkb:Doering–Parikh_oxidation
|
gptkbp:bfsLayer |
5
|