Statements (26)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
|
| gptkbp:advantage |
mild conditions
|
| gptkbp:application |
organic synthesis
|
| gptkbp:byproduct |
hydrogen chloride
dimethyl sulfide oxide succinimide |
| gptkbp:convertedTo |
primary alcohols to aldehydes
secondary alcohols to ketones |
| https://www.w3.org/2000/01/rdf-schema#label |
Corey–Kim oxidation
|
| gptkbp:limitation |
can lead to overoxidation if not controlled
dimethyl sulfide is malodorous and toxic |
| gptkbp:mechanismOfAction |
activation of alcohol by N-chlorosuccinimide and dimethyl sulfide
|
| gptkbp:namedAfter |
gptkb:Choung_Un_Kim
gptkb:E.J._Corey |
| gptkbp:publicationYear |
1972
|
| gptkbp:publishedIn |
gptkb:Journal_of_the_American_Chemical_Society
|
| gptkbp:relatedTo |
gptkb:Swern_oxidation
gptkb:Parikh–Doering_oxidation gptkb:Pfitzner–Moffatt_oxidation |
| gptkbp:solvent |
dichloromethane
|
| gptkbp:type |
oxidation
|
| gptkbp:usesReagent |
N-chlorosuccinimide
dimethyl sulfide triethylamine |
| gptkbp:bfsParent |
gptkb:Elias_J._Corey
|
| gptkbp:bfsLayer |
5
|