Corey–House–Posner–Whitesides reaction
GPTKB entity
Statements (22)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
|
| gptkbp:alsoKnownAs |
Corey–House reaction
|
| gptkbp:application |
synthesis of complex alkanes
|
| gptkbp:category |
organometallic chemistry
name reaction |
| gptkbp:discoveredIn |
1972
|
| https://www.w3.org/2000/01/rdf-schema#label |
Corey–House–Posner–Whitesides reaction
|
| gptkbp:involves |
alkyl halides
organocopper reagents |
| gptkbp:limitation |
secondary and tertiary halides give poor yields
works best with primary alkyl halides |
| gptkbp:mechanismOfAction |
nucleophilic substitution
|
| gptkbp:namedAfter |
gptkb:George_Whitesides
gptkb:Herbert_O._House gptkb:E.J._Corey gptkb:Gary_Posner |
| gptkbp:product |
alkene
|
| gptkbp:publishedIn |
gptkb:Journal_of_the_American_Chemical_Society
|
| gptkbp:type |
coupling reaction
carbon–carbon bond formation |
| gptkbp:bfsParent |
gptkb:Corey–House_synthesis
|
| gptkbp:bfsLayer |
6
|