Statements (23)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
|
| gptkbp:advantage |
mild conditions preserve sensitive groups
|
| gptkbp:alsoKnownAs |
Zemplén deacetylation
|
| gptkbp:criteria |
selective for acetyl groups
|
| gptkbp:discoveredBy |
Kálmán Zemplén
|
| gptkbp:discoveredIn |
1920s
|
| https://www.w3.org/2000/01/rdf-schema#label |
Zemplén reaction
|
| gptkbp:mainActivity |
deacetylation of esters
removal of acetyl protecting groups |
| gptkbp:mechanismOfAction |
base-catalyzed ester hydrolysis
|
| gptkbp:namedAfter |
Kálmán Zemplén
|
| gptkbp:product |
gptkb:methyl_acetate
free hydroxyl groups |
| gptkbp:reactant |
sodium methoxide
|
| gptkbp:reactionCondition |
mild basic conditions
|
| gptkbp:solvent |
gptkb:methanol
|
| gptkbp:substrate |
acetylated glycosides
acetylated sugars |
| gptkbp:type |
deprotection reaction
|
| gptkbp:usedIn |
carbohydrate chemistry
organic synthesis |
| gptkbp:bfsParent |
gptkb:Géza_Zemplén
|
| gptkbp:bfsLayer |
8
|