Thorpe–Ingold effect

GPTKB entity

Statements (17)
Predicate Object
gptkbp:instanceOf chemical effect
gptkbp:alsoKnownAs gem-dimethyl effect
gptkbp:category physical organic chemistry
gptkbp:causedBy introduction of geminal substituents
gptkbp:describes acceleration of cyclization reactions
gptkbp:effect reaction rate
molecular geometry
gptkbp:example gem-dimethyl groups increasing cyclization rate
gptkbp:firstDescribed 1915
https://www.w3.org/2000/01/rdf-schema#label Thorpe–Ingold effect
gptkbp:namedAfter gptkb:Christopher_Kelk_Ingold
Jocelyn Field Thorpe
gptkbp:observedBy organic chemistry
gptkbp:relatedTo steric effects
cyclization reactions
gptkbp:bfsParent gptkb:John_A._Thorpe
gptkbp:bfsLayer 7