Statements (21)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
|
| gptkbp:category |
organic chemistry
oxidation reaction enantioselective synthesis |
| gptkbp:developedBy |
gptkb:K._Barry_Sharpless
1980 |
| https://www.w3.org/2000/01/rdf-schema#label |
Sharpless dihydroxylation
|
| gptkbp:NobelPrizeYear |
gptkb:K._Barry_Sharpless
|
| gptkbp:notableFor |
enantioselectivity
|
| gptkbp:product |
vicinal diol
|
| gptkbp:solvent |
gptkb:water
gptkb:tert-butanol |
| gptkbp:substrate |
alkene
|
| gptkbp:type |
asymmetric dihydroxylation
|
| gptkbp:usesCo-catalyst |
chiral ligand
potassium ferricyanide |
| gptkbp:usesLigand |
(DHQ)2PHAL
(DHQD)2PHAL |
| gptkbp:usesReagent |
osmium tetroxide
|
| gptkbp:bfsParent |
gptkb:Sharpless_aminohydroxylation
|
| gptkbp:bfsLayer |
7
|