Morita–Baylis–Hillman reaction

GPTKB entity

Statements (25)
Predicate Object
gptkbp:instanceOf gptkb:chemical_compound
gptkbp:alsoKnownAs Baylis–Hillman reaction
MBH reaction
gptkbp:application pharmaceutical chemistry
organic synthesis
gptkbp:catalyzes phosphine
tertiary amine
gptkbp:category organocatalysis
name reaction
carbon–carbon bond formation
gptkbp:firstReported 1972
https://www.w3.org/2000/01/rdf-schema#label Morita–Baylis–Hillman reaction
gptkbp:involves aldehyde
ketone
nucleophilic addition
α,β-unsaturated carbonyl compound
gptkbp:mechanismOfAction enolate intermediate
nucleophile-catalyzed coupling
gptkbp:namedAfter Anthony B. Baylis
Ken-ichi Morita
Melville S. Hillman
gptkbp:product allylic alcohol
gptkbp:type carbon–carbon bond-forming reaction
gptkbp:bfsParent gptkb:Morita_Array
gptkbp:bfsLayer 7