Statements (23)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
chemical equation
empirical relationship |
| gptkbp:appliesTo |
aromatic compounds
benzoic acid derivatives |
| gptkbp:category |
chemistry equations
|
| gptkbp:describes |
effect of substituents on equilibrium constants
effect of substituents on reaction rates |
| gptkbp:field |
physical organic chemistry
|
| gptkbp:form |
log(k/k0) = ρσ
|
| https://www.w3.org/2000/01/rdf-schema#label |
Hammett equation
|
| gptkbp:introducedIn |
1937
|
| gptkbp:namedAfter |
Louis Plack Hammett
|
| gptkbp:parameter |
rho (ρ)
sigma (σ) |
| gptkbp:publishedIn |
gptkb:Journal_of_the_American_Chemical_Society
|
| gptkbp:relatedTo |
Taft equation
Yukawa–Tsuno equation linear free-energy relationships |
| gptkbp:rhoValue |
depends on reaction type
|
| gptkbp:sigmaValue |
depends on substituent and position
|
| gptkbp:usedFor |
quantifying electronic effects
|
| gptkbp:bfsParent |
gptkb:Louis_P._Hammett
|
| gptkbp:bfsLayer |
7
|