Grubbs' twenty-sixth-generation catalyst
GPTKB entity
Statements (54)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
catalyst
|
| gptkbp:application |
polymerization
|
| gptkbp:characteristics |
high activity
high stability broad substrate scope |
| gptkbp:composedOf |
X-ray crystallography
spectroscopy elemental analysis chromatography crystallization mass spectrometry NMR spectroscopy purification thermal analysis reaction optimization computational modeling characterization electrochemical analysis complexation industrial application ligand exchange metalation precursor synthesis scale-up production |
| gptkbp:contains |
ruthenium
|
| gptkbp:developedBy |
gptkb:Robert_H._Grubbs
|
| gptkbp:dissolved |
soluble in organic solvents
|
| gptkbp:financial_aid |
thermally stable
air stable |
| gptkbp:gameMechanics |
product formation
metathesis mechanism catalytic cycle regeneration of catalyst substrate activation |
| https://www.w3.org/2000/01/rdf-schema#label |
Grubbs' twenty-sixth-generation catalyst
|
| gptkbp:improves |
reaction efficiency
|
| gptkbp:internationalClassification |
ring-closing metathesis
self-metathesis cross metathesis |
| gptkbp:introduced |
2005
|
| gptkbp:market |
available from chemical suppliers
|
| gptkbp:related_to |
N-heterocyclic carbene
|
| gptkbp:relatedTo |
green chemistry
sustainable chemistry organometallic chemistry metathesis reactions |
| gptkbp:releaseYear |
2005
|
| gptkbp:researchField |
organic synthesis
catalysis polymer science |
| gptkbp:significance |
gptkb:Nobel_Prize_in_Chemistry_2005
|
| gptkbp:successor |
gptkb:Grubbs'_fifth-generation_catalyst
|
| gptkbp:type |
transition metal complex
|
| gptkbp:usedIn |
olefin metathesis
|