Statements (48)
| Predicate | Object |
|---|---|
| gptkbp:instance_of |
gptkb:chemical_compound
|
| gptkbp:can_be_used_to |
synthesize alcohols
prepare organometallic compounds |
| gptkbp:can_create |
carbanions
organocopper intermediates |
| gptkbp:contains |
gptkb:copper
alkyl groups |
| gptkbp:financial_stability |
dry solvents
|
| gptkbp:formed |
reaction of copper(I) iodide with organolithium compounds
|
| https://www.w3.org/2000/01/rdf-schema#label |
Gilman reagent
|
| gptkbp:is_a |
gptkb:chemical_compound
nucleophile reactive intermediate synthetic intermediate reagent copper reagent nucleophilic agent nucleophilic reagent organocopper reagent organometallic reagent synthetic reagent |
| gptkbp:is_less_reactive_than |
Grignard reagents
organolithium reagents |
| gptkbp:is_less_toxic_than |
Grignard reagents
|
| gptkbp:is_prepared_from |
lithium diorganocopper reagents
|
| gptkbp:is_used_in |
nucleophilic substitution reactions
cross-coupling reactions deprotonation reactions the formation of C-C bonds the preparation of alkynes from alkyl halides the synthesis of aldehydes the synthesis of amines the synthesis of carboxylic acids the synthesis of complex molecules the synthesis of esters the synthesis of ethers the synthesis of ketones |
| gptkbp:is_used_to |
form carbon-carbon bonds
|
| gptkbp:is_used_to_synthesize |
alkenes
|
| gptkbp:named_after |
gptkb:Henry_Gilman
|
| gptkbp:produces |
alkynes
|
| gptkbp:sensitivity |
moisture
|
| gptkbp:used_in |
organic synthesis
|
| gptkbp:was_a_response_to |
alkyl halides
carbonyl compounds |
| gptkbp:bfsParent |
gptkb:Corey–_Fuchs_reaction
gptkb:Corey–_House_reaction |
| gptkbp:bfsLayer |
6
|