Rydberg series

E679852

The Rydberg series is a sequence of spectral lines in atoms that converge toward an ionization limit, described by the Rydberg formula and fundamental to understanding atomic energy levels.

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Rydberg series canonical 1

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Predicate Object
instanceOf concept in atomic physics
spectral series
appliesTo hydrogen atom
hydrogen-like atoms
many-electron atoms
characterizedBy effective quantum defect in non-hydrogenic atoms
principal quantum number n
series limit energy
convergesTo ionization limit
describes sequence of spectral lines in atoms
energyLevelsFollow En = -R_H Z^2 / n^2 for hydrogen-like atoms
fundamentalTo understanding atomic energy levels
hasApplication astrophysical spectroscopy
determination of Rydberg constant
identification of atomic and ionic species in spectra
plasma diagnostics
precision tests of quantum electrodynamics in simple atoms
spectroscopic determination of ionization energies
hasExample Balmer series
Brackett series
Humphreys series
Lyman series
Paschen series
Pfund series
hasHistoricalSignificance motivated development of Bohr atomic model
provided early evidence for quantized atomic energy levels
hasProperty line intensities depend on transition probabilities and population of initial states
series limit corresponds to transition to continuum state
spectral lines accumulate near series limit
spectral lines become more closely spaced at higher quantum numbers
namedAfter Johannes Rydberg
occursIn absorption spectra
atomic spectra
emission spectra
relatedTo Bohr model of the atom
Rydberg formula
Rydberg states
bound-bound electronic transitions
bound-free electronic transitions
high principal quantum number electronic states
photoionization threshold
quantization of energy levels
studiedIn astrophysics
atomic spectroscopy
plasma physics
quantum mechanics
usesConstant Rydberg constant
wavelengthsFollow 1/λ = R Z^2 (1/n1^2 - 1/n2^2) for hydrogen-like atoms

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Rydberg atom relatedTo Rydberg series
subject linked to: Rydberg atoms