Statements (18)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
|
| gptkbp:application |
synthesis of cyclic compounds
|
| gptkbp:catalyzes |
gptkb:foundation
|
| gptkbp:category |
carbon-carbon bond forming reaction
|
| gptkbp:discoveredIn |
1894
|
| gptkbp:field |
organic chemistry
|
| https://www.w3.org/2000/01/rdf-schema#label |
Dieckmann condensation
|
| gptkbp:mechanismOfAction |
nucleophilic acyl substitution
enolate formation |
| gptkbp:namedAfter |
Walter Dieckmann
|
| gptkbp:product |
β-keto ester
|
| gptkbp:reactant |
diester
|
| gptkbp:reactionCondition |
non-aqueous solvent
strong base (e.g., sodium ethoxide) |
| gptkbp:relatedTo |
gptkb:Claisen_condensation
|
| gptkbp:type |
intramolecular Claisen condensation
|
| gptkbp:bfsParent |
gptkb:Claisen_condensation
|
| gptkbp:bfsLayer |
7
|