Crossed Claisen condensation
GPTKB entity
Statements (22)
Predicate | Object |
---|---|
gptkbp:instanceOf |
gptkb:chemical_compound
condensation reaction carbon-carbon bond forming reaction |
gptkbp:application |
synthesis of β-diketones
synthesis of β-keto esters |
gptkbp:category |
named reaction
|
gptkbp:commonIn |
sodium hydride
sodium ethoxide |
gptkbp:criteria |
best with one reactant lacking alpha hydrogens
|
gptkbp:distinctiveFeature |
use of two different esters
|
gptkbp:hasReactant |
estrogen
enolate |
https://www.w3.org/2000/01/rdf-schema#label |
Crossed Claisen condensation
|
gptkbp:mechanismOfAction |
nucleophilic acyl substitution
|
gptkbp:namedAfter |
gptkb:Ludwig_Claisen
|
gptkbp:product |
gptkb:beer
β-keto ester |
gptkbp:relatedTo |
gptkb:Claisen_condensation
|
gptkbp:requiresBase |
strong base
|
gptkbp:sideProduct |
gptkb:beer
|
gptkbp:bfsParent |
gptkb:Claisen_condensation
|
gptkbp:bfsLayer |
7
|