Barton–McCombie deoxygenation
GPTKB entity
Statements (22)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
gptkb:chemical_compound
|
| gptkbp:alternativeTo |
phosphorus-based reagents
tris(trimethylsilyl)silane |
| gptkbp:application |
organic synthesis
removal of hydroxyl group |
| gptkbp:category |
name reaction
reduction reaction |
| gptkbp:discoveredIn |
1975
|
| https://www.w3.org/2000/01/rdf-schema#label |
Barton–McCombie deoxygenation
|
| gptkbp:mainReagent |
gptkb:AIBN
thionocarbonate tributyltin hydride xanthate ester |
| gptkbp:mechanismOfAction |
radical chain mechanism
|
| gptkbp:namedAfter |
gptkb:Derek_Barton
gptkb:Stuart_W._McCombie |
| gptkbp:product |
alkene
|
| gptkbp:substrate |
gptkb:beer
|
| gptkbp:type |
deoxygenation
radical reaction |
| gptkbp:bfsParent |
gptkb:Sir_Derek_Barton
|
| gptkbp:bfsLayer |
4
|