Statements (40)
| Predicate | Object |
|---|---|
| gptkbp:instanceOf |
polymerization technique
|
| gptkbp:advantage |
precise control over polymer architecture
tolerance to functional groups |
| gptkbp:application |
nanomaterials
coatings biomedical materials graft polymers block copolymers functional polymers star polymers |
| gptkbp:catalyzes |
transition metal complexes
|
| gptkbp:commonCatalyst |
gptkb:copper(I)_bromide
|
| gptkbp:enables |
synthesis of polymers with controlled molecular weight
synthesis of polymers with narrow molecular weight distribution |
| gptkbp:field |
polymer chemistry
|
| gptkbp:fullName |
gptkb:Atom_Transfer_Radical_Polymerization
|
| https://www.w3.org/2000/01/rdf-schema#label |
ATRP
|
| gptkbp:improves |
ARGET ATRP
ICAR ATRP SARA ATRP electrochemically mediated ATRP photoinduced ATRP |
| gptkbp:initiator |
alkyl halides
|
| gptkbp:introducedIn |
1995
|
| gptkbp:inventedBy |
gptkb:Krzysztof_Matyjaszewski
|
| gptkbp:limitation |
metal contamination
requirement for deoxygenation |
| gptkbp:mechanismOfAction |
reversible activation-deactivation
|
| gptkbp:monomer |
gptkb:styrene
methyl methacrylate methacrylates acrylates |
| gptkbp:notableInvention |
US5525672A
|
| gptkbp:notablePublication |
Matyjaszewski, K. et al., Science, 1995, 272, 866-868
|
| gptkbp:relatedTo |
NMP (Nitroxide Mediated Polymerization)
RAFT polymerization living polymerization |
| gptkbp:usedFor |
controlled radical polymerization
|
| gptkbp:bfsParent |
gptkb:Chuu
|
| gptkbp:bfsLayer |
7
|