Triple
T8665142
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Larry E. Overman |
E205649
|
entity |
| Predicate | notableConcept |
P201
|
FINISHED |
| Object | Overman rearrangement |
E749332
|
NE FINISHED |
How this triple was built (2 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Overman rearrangement | Statement: [Larry E. Overman, notableConcept, Overman rearrangement]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Overman rearrangement Context triple: [Larry E. Overman, notableConcept, Overman rearrangement]
-
A.
Overman rearrangement
chosen
The Overman rearrangement is an organic chemical reaction that converts allylic alcohol derivatives into allylic amines via a [3,3]-sigmatropic rearrangement of allylic trichloroacetimidates.
-
B.
Stork–Danheiser rearrangement
The Stork–Danheiser rearrangement is an organic reaction that transforms certain allylic alcohol derivatives into rearranged carbonyl compounds via a sigmatropic shift, widely used in complex molecule synthesis.
-
C.
Eschenmoser–Claisen rearrangement
The Eschenmoser–Claisen rearrangement is a variant of the Claisen rearrangement in organic chemistry that converts allylic alcohols and amides into γ,δ-unsaturated carbonyl compounds via a [3,3]-sigmatropic rearrangement.
-
D.
Barton reaction
The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
-
E.
Robinson annulation reaction
The Robinson annulation reaction is a classic organic chemistry transformation that forms six-membered rings by combining a Michael addition with an intramolecular aldol condensation, widely used in the synthesis of complex cyclic molecules and natural products.
- F. None of above.
- G. Unsure - the case is ambiguous/there is not enough information to decide.
Provenance (3 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69ca83516ae88190aefe034b3bc589e3 |
completed | March 30, 2026, 2:06 p.m. |
| NER | Named-entity recognition | batch_69cc48a0ae108190b33dadcc3cb18949 |
completed | March 31, 2026, 10:20 p.m. |
| NED1 | Entity disambiguation (via context triple) | batch_69cef3898bf88190959b361638d032de |
completed | April 2, 2026, 10:54 p.m. |
Created at: March 30, 2026, 6:30 p.m.