Triple

T747529
Position Surface form Disambiguated ID Type / Status
Subject Christopher Longuet-Higgins E15375 entity
Predicate notableWork P4 FINISHED
Object Longuet-Higgins theorem in molecular symmetry
The Longuet-Higgins theorem in molecular symmetry is a fundamental result in theoretical chemistry that relates molecular symmetry properties to electronic state degeneracies and the occurrence of phenomena such as the Jahn–Teller effect.
E88919 NE FINISHED

How this triple was built (4 steps)

Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.

NER Named-entity recognition gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Longuet-Higgins theorem in molecular symmetry | Statement: [Christopher Longuet-Higgins, notableWork, Longuet-Higgins theorem in molecular symmetry]
NED1 Entity disambiguation (via context triple) gpt-5-mini-2025-08-07
Target entity: Longuet-Higgins theorem in molecular symmetry
Context triple: [Christopher Longuet-Higgins, notableWork, Longuet-Higgins theorem in molecular symmetry]
  • A. Herzberg–Teller approximation
    The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
  • B. The Nature of the Chemical Bond
    The Nature of the Chemical Bond is a landmark chemistry book by Linus Pauling that systematically explains chemical bonding using quantum mechanics and became one of the most influential scientific texts of the 20th century.
  • C. Brillouin–Wigner perturbation theory
    Brillouin–Wigner perturbation theory is a formulation of quantum mechanical perturbation theory that uses an energy-dependent effective Hamiltonian to obtain improved approximations to eigenvalues and eigenstates.
  • D. Rayleigh–Schrödinger perturbation theory
    Rayleigh–Schrödinger perturbation theory is a fundamental method in quantum mechanics for approximating the energies and states of a system by treating interactions as small corrections to an exactly solvable problem.
  • E. Born–Oppenheimer approximation
    The Born–Oppenheimer approximation is a fundamental method in molecular quantum mechanics that simplifies calculations by treating nuclear motion as much slower than electronic motion, allowing their behaviors to be separated.
  • F. None of above. chosen
  • G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg Description generation gpt-5.1
Instruction
Generate a one-sentence description of the target entity. 
You are given a context triple in the form (subject, predicate, object), where the object is the target entity. 
# Instructions
Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. 
Avoid repeating the information from the triple, unless really essential.
# Response Format
Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: Longuet-Higgins theorem in molecular symmetry
Triple: [Christopher Longuet-Higgins, notableWork, Longuet-Higgins theorem in molecular symmetry]
Generated description
The Longuet-Higgins theorem in molecular symmetry is a fundamental result in theoretical chemistry that relates molecular symmetry properties to electronic state degeneracies and the occurrence of phenomena such as the Jahn–Teller effect.
NED2 Entity disambiguation (via description) gpt-5-mini-2025-08-07
Target entity: Longuet-Higgins theorem in molecular symmetry
Target entity description: The Longuet-Higgins theorem in molecular symmetry is a fundamental result in theoretical chemistry that relates molecular symmetry properties to electronic state degeneracies and the occurrence of phenomena such as the Jahn–Teller effect.
  • A. Herzberg–Teller approximation
    The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
  • B. The Nature of the Chemical Bond
    The Nature of the Chemical Bond is a landmark chemistry book by Linus Pauling that systematically explains chemical bonding using quantum mechanics and became one of the most influential scientific texts of the 20th century.
  • C. Brillouin–Wigner perturbation theory
    Brillouin–Wigner perturbation theory is a formulation of quantum mechanical perturbation theory that uses an energy-dependent effective Hamiltonian to obtain improved approximations to eigenvalues and eigenstates.
  • D. Rayleigh–Schrödinger perturbation theory
    Rayleigh–Schrödinger perturbation theory is a fundamental method in quantum mechanics for approximating the energies and states of a system by treating interactions as small corrections to an exactly solvable problem.
  • E. Born–Oppenheimer approximation
    The Born–Oppenheimer approximation is a fundamental method in molecular quantum mechanics that simplifies calculations by treating nuclear motion as much slower than electronic motion, allowing their behaviors to be separated.
  • F. None of above. chosen

Provenance (5 batches)

The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.

Step Stage Batch ID Status When
creating Elicitation batch_69a49358aa308190adbc9b5a0a2adcf9 completed March 1, 2026, 7:28 p.m.
NER Named-entity recognition batch_69a4a62dd1bc819094a3814654448ae3 completed March 1, 2026, 8:48 p.m.
NED1 Entity disambiguation (via context triple) batch_69a654e664e4819081badaf0ba0d86e5 completed March 3, 2026, 3:26 a.m.
NEDg Description generation batch_69a655e0a2608190801fb67856bc2ac4 completed March 3, 2026, 3:30 a.m.
NED2 Entity disambiguation (via description) batch_69a65704a964819097ad5074e83303b4 completed March 3, 2026, 3:35 a.m.
Created at: March 1, 2026, 7:37 p.m.