Triple
T7150552
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Hartree–Fock method |
E166679
|
entity |
| Predicate | hasVariant |
P455
|
FINISHED |
| Object |
time-dependent Hartree–Fock
Time-dependent Hartree–Fock is an extension of the Hartree–Fock approximation that describes the real-time evolution of interacting many-electron systems under time-dependent external fields.
|
E166679
|
NE FINISHED |
How this triple was built (4 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: time-dependent Hartree–Fock | Statement: [Hartree–Fock method, hasVariant, time-dependent Hartree–Fock]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: time-dependent Hartree–Fock Context triple: [Hartree–Fock method, hasVariant, time-dependent Hartree–Fock]
-
A.
Hartree–Fock method
The Hartree–Fock method is an approximate quantum mechanical approach for determining the electronic structure of atoms, molecules, and solids by modeling electrons as occupying self-consistent single-particle orbitals.
-
B.
Brillouin–Wigner perturbation theory
Brillouin–Wigner perturbation theory is a formulation of quantum mechanical perturbation theory that uses an energy-dependent effective Hamiltonian to obtain improved approximations to eigenvalues and eigenstates.
-
C.
Herzberg–Teller approximation
The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
-
D.
Born–Oppenheimer approximation
The Born–Oppenheimer approximation is a fundamental method in molecular quantum mechanics that simplifies calculations by treating nuclear motion as much slower than electronic motion, allowing their behaviors to be separated.
-
E.
Rayleigh–Schrödinger perturbation theory
Rayleigh–Schrödinger perturbation theory is a fundamental method in quantum mechanics for approximating the energies and states of a system by treating interactions as small corrections to an exactly solvable problem.
- F. None of above. chosen
- G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg
Description generation
gpt-5.1
Instruction
Generate a one-sentence description of the target entity. You are given a context triple in the form (subject, predicate, object), where the object is the target entity. # Instructions Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. Avoid repeating the information from the triple, unless really essential. # Response Format Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: time-dependent Hartree–Fock Triple: [Hartree–Fock method, hasVariant, time-dependent Hartree–Fock]
Generated description
Time-dependent Hartree–Fock is an extension of the Hartree–Fock approximation that describes the real-time evolution of interacting many-electron systems under time-dependent external fields.
NED2
Entity disambiguation (via description)
gpt-5-mini-2025-08-07
Target entity: time-dependent Hartree–Fock Target entity description: Time-dependent Hartree–Fock is an extension of the Hartree–Fock approximation that describes the real-time evolution of interacting many-electron systems under time-dependent external fields.
-
A.
Hartree–Fock method
chosen
The Hartree–Fock method is an approximate quantum mechanical approach for determining the electronic structure of atoms, molecules, and solids by modeling electrons as occupying self-consistent single-particle orbitals.
-
B.
Brillouin–Wigner perturbation theory
Brillouin–Wigner perturbation theory is a formulation of quantum mechanical perturbation theory that uses an energy-dependent effective Hamiltonian to obtain improved approximations to eigenvalues and eigenstates.
-
C.
Herzberg–Teller approximation
The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
-
D.
Born–Oppenheimer approximation
The Born–Oppenheimer approximation is a fundamental method in molecular quantum mechanics that simplifies calculations by treating nuclear motion as much slower than electronic motion, allowing their behaviors to be separated.
-
E.
Rayleigh–Schrödinger perturbation theory
Rayleigh–Schrödinger perturbation theory is a fundamental method in quantum mechanics for approximating the energies and states of a system by treating interactions as small corrections to an exactly solvable problem.
- F. None of above.
Provenance (5 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69c68886779c8190a8e3fbabffe68253 |
completed | March 27, 2026, 1:39 p.m. |
| NER | Named-entity recognition | batch_69c6e7f28b188190b1732ca711666531 |
completed | March 27, 2026, 8:26 p.m. |
| NED1 | Entity disambiguation (via context triple) | batch_69c7ada940e08190b16e97e363801e75 |
completed | March 28, 2026, 10:30 a.m. |
| NEDg | Description generation | batch_69c7ae5767408190860c1c7bc3a769fa |
completed | March 28, 2026, 10:32 a.m. |
| NED2 | Entity disambiguation (via description) | batch_69c7aeb68c3481909c6dff8ee51349ab |
completed | March 28, 2026, 10:34 a.m. |
Created at: March 27, 2026, 2:46 p.m.