Triple

T6994979
Position Surface form Disambiguated ID Type / Status
Subject David A. Evans E162185 entity
Predicate knownFor P22 FINISHED
Object Evans aldol reaction
The Evans aldol reaction is a stereoselective carbon–carbon bond-forming reaction that uses chiral N-acyl oxazolidinone auxiliaries to control the configuration of aldol products.
E635933 NE FINISHED

How this triple was built (4 steps)

Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.

NER Named-entity recognition gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Evans aldol reaction | Statement: [David A. Evans, knownFor, Evans aldol reaction]
NED1 Entity disambiguation (via context triple) gpt-5-mini-2025-08-07
Target entity: Evans aldol reaction
Context triple: [David A. Evans, knownFor, Evans aldol reaction]
  • A. Barton reaction
    The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
  • B. Robinson annulation reaction
    The Robinson annulation reaction is a classic organic chemistry transformation that forms six-membered rings by combining a Michael addition with an intramolecular aldol condensation, widely used in the synthesis of complex cyclic molecules and natural products.
  • C. Eschenmoser–Claisen rearrangement
    The Eschenmoser–Claisen rearrangement is a variant of the Claisen rearrangement in organic chemistry that converts allylic alcohols and amides into γ,δ-unsaturated carbonyl compounds via a [3,3]-sigmatropic rearrangement.
  • D. Norrish reaction
    The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
  • E. Eschenmoser sulfide contraction
    Eschenmoser sulfide contraction is an organic rearrangement reaction that converts certain sulfur-containing intermediates into carbonyl compounds, widely used in complex molecule and natural product synthesis.
  • F. None of above. chosen
  • G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg Description generation gpt-5.1
Instruction
Generate a one-sentence description of the target entity. 
You are given a context triple in the form (subject, predicate, object), where the object is the target entity. 
# Instructions
Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. 
Avoid repeating the information from the triple, unless really essential.
# Response Format
Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: Evans aldol reaction
Triple: [David A. Evans, knownFor, Evans aldol reaction]
Generated description
The Evans aldol reaction is a stereoselective carbon–carbon bond-forming reaction that uses chiral N-acyl oxazolidinone auxiliaries to control the configuration of aldol products.
NED2 Entity disambiguation (via description) gpt-5-mini-2025-08-07
Target entity: Evans aldol reaction
Target entity description: The Evans aldol reaction is a stereoselective carbon–carbon bond-forming reaction that uses chiral N-acyl oxazolidinone auxiliaries to control the configuration of aldol products.
  • A. Barton reaction
    The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
  • B. Robinson annulation reaction
    The Robinson annulation reaction is a classic organic chemistry transformation that forms six-membered rings by combining a Michael addition with an intramolecular aldol condensation, widely used in the synthesis of complex cyclic molecules and natural products.
  • C. Eschenmoser–Claisen rearrangement
    The Eschenmoser–Claisen rearrangement is a variant of the Claisen rearrangement in organic chemistry that converts allylic alcohols and amides into γ,δ-unsaturated carbonyl compounds via a [3,3]-sigmatropic rearrangement.
  • D. Norrish reaction
    The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
  • E. Eschenmoser sulfide contraction
    Eschenmoser sulfide contraction is an organic rearrangement reaction that converts certain sulfur-containing intermediates into carbonyl compounds, widely used in complex molecule and natural product synthesis.
  • F. None of above. chosen

Provenance (5 batches)

The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.

Step Stage Batch ID Status When
creating Elicitation batch_69c68857ffc08190857dc62cd5253777 completed March 27, 2026, 1:38 p.m.
NER Named-entity recognition batch_69c6dbec259c8190bb4cfbc1ff6fc786 completed March 27, 2026, 7:35 p.m.
NED1 Entity disambiguation (via context triple) batch_69c76a1adec88190a769ec7af0fa7b51 completed March 28, 2026, 5:41 a.m.
NEDg Description generation batch_69c76aac21448190ac2b94c836f2f725 completed March 28, 2026, 5:44 a.m.
NED2 Entity disambiguation (via description) batch_69c76b3efc0081909e506f9a828d4fd8 completed March 28, 2026, 5:46 a.m.
Created at: March 27, 2026, 2:32 p.m.