Triple
T6994979
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | David A. Evans |
E162185
|
entity |
| Predicate | knownFor |
P22
|
FINISHED |
| Object |
Evans aldol reaction
The Evans aldol reaction is a stereoselective carbon–carbon bond-forming reaction that uses chiral N-acyl oxazolidinone auxiliaries to control the configuration of aldol products.
|
E635933
|
NE FINISHED |
How this triple was built (4 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Evans aldol reaction | Statement: [David A. Evans, knownFor, Evans aldol reaction]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Evans aldol reaction Context triple: [David A. Evans, knownFor, Evans aldol reaction]
-
A.
Barton reaction
The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
-
B.
Robinson annulation reaction
The Robinson annulation reaction is a classic organic chemistry transformation that forms six-membered rings by combining a Michael addition with an intramolecular aldol condensation, widely used in the synthesis of complex cyclic molecules and natural products.
-
C.
Eschenmoser–Claisen rearrangement
The Eschenmoser–Claisen rearrangement is a variant of the Claisen rearrangement in organic chemistry that converts allylic alcohols and amides into γ,δ-unsaturated carbonyl compounds via a [3,3]-sigmatropic rearrangement.
-
D.
Norrish reaction
The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
-
E.
Eschenmoser sulfide contraction
Eschenmoser sulfide contraction is an organic rearrangement reaction that converts certain sulfur-containing intermediates into carbonyl compounds, widely used in complex molecule and natural product synthesis.
- F. None of above. chosen
- G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg
Description generation
gpt-5.1
Instruction
Generate a one-sentence description of the target entity. You are given a context triple in the form (subject, predicate, object), where the object is the target entity. # Instructions Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. Avoid repeating the information from the triple, unless really essential. # Response Format Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: Evans aldol reaction Triple: [David A. Evans, knownFor, Evans aldol reaction]
Generated description
The Evans aldol reaction is a stereoselective carbon–carbon bond-forming reaction that uses chiral N-acyl oxazolidinone auxiliaries to control the configuration of aldol products.
NED2
Entity disambiguation (via description)
gpt-5-mini-2025-08-07
Target entity: Evans aldol reaction Target entity description: The Evans aldol reaction is a stereoselective carbon–carbon bond-forming reaction that uses chiral N-acyl oxazolidinone auxiliaries to control the configuration of aldol products.
-
A.
Barton reaction
The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
-
B.
Robinson annulation reaction
The Robinson annulation reaction is a classic organic chemistry transformation that forms six-membered rings by combining a Michael addition with an intramolecular aldol condensation, widely used in the synthesis of complex cyclic molecules and natural products.
-
C.
Eschenmoser–Claisen rearrangement
The Eschenmoser–Claisen rearrangement is a variant of the Claisen rearrangement in organic chemistry that converts allylic alcohols and amides into γ,δ-unsaturated carbonyl compounds via a [3,3]-sigmatropic rearrangement.
-
D.
Norrish reaction
The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
-
E.
Eschenmoser sulfide contraction
Eschenmoser sulfide contraction is an organic rearrangement reaction that converts certain sulfur-containing intermediates into carbonyl compounds, widely used in complex molecule and natural product synthesis.
- F. None of above. chosen
Provenance (5 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69c68857ffc08190857dc62cd5253777 |
completed | March 27, 2026, 1:38 p.m. |
| NER | Named-entity recognition | batch_69c6dbec259c8190bb4cfbc1ff6fc786 |
completed | March 27, 2026, 7:35 p.m. |
| NED1 | Entity disambiguation (via context triple) | batch_69c76a1adec88190a769ec7af0fa7b51 |
completed | March 28, 2026, 5:41 a.m. |
| NEDg | Description generation | batch_69c76aac21448190ac2b94c836f2f725 |
completed | March 28, 2026, 5:44 a.m. |
| NED2 | Entity disambiguation (via description) | batch_69c76b3efc0081909e506f9a828d4fd8 |
completed | March 28, 2026, 5:46 a.m. |
Created at: March 27, 2026, 2:32 p.m.