Triple
T6765533
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Henry Eyring |
E154708
|
entity |
| Predicate | notableWork |
P4
|
FINISHED |
| Object |
The Theory of Rate Processes (book, co-authored)
The Theory of Rate Processes is a foundational scientific book that systematically develops the theory of chemical reaction rates and laid the groundwork for modern transition state theory in physical chemistry.
|
E617544
|
NE FINISHED |
How this triple was built (4 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: The Theory of Rate Processes (book, co-authored) | Statement: [Henry Eyring, notableWork, The Theory of Rate Processes (book, co-authored)]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: The Theory of Rate Processes (book, co-authored) Context triple: [Henry Eyring, notableWork, The Theory of Rate Processes (book, co-authored)]
-
A.
Arrhenius equation for temperature dependence of reaction rates
The Arrhenius equation for temperature dependence of reaction rates is a fundamental formula in chemical kinetics that quantitatively relates a reaction’s rate constant to temperature and activation energy, explaining why reactions speed up as temperature increases.
-
B.
Kramers turnover theory
Kramers turnover theory is a foundational concept in chemical physics that describes how reaction rates depend on friction or solvent viscosity, predicting a maximum (turnover) as friction varies.
-
C.
Taube mechanism in electron transfer
The Taube mechanism in electron transfer is a foundational concept in inorganic chemistry that explains how electrons are transferred between metal complexes through ligand-bridged, often inner-sphere, pathways.
-
D.
Fick's first law of diffusion
Fick's first law of diffusion is a fundamental physical law that relates the diffusive flux of particles to the spatial gradient of their concentration, describing how substances move from regions of high to low concentration.
-
E.
Thermodynamics and the Free Energy of Chemical Substances
Thermodynamics and the Free Energy of Chemical Substances is a foundational 1923 textbook by Gilbert N. Lewis and Merle Randall that systematically applied thermodynamic principles to chemical equilibria and free energy, helping to establish modern physical chemistry.
- F. None of above. chosen
- G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg
Description generation
gpt-5.1
Instruction
Generate a one-sentence description of the target entity. You are given a context triple in the form (subject, predicate, object), where the object is the target entity. # Instructions Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. Avoid repeating the information from the triple, unless really essential. # Response Format Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: The Theory of Rate Processes (book, co-authored) Triple: [Henry Eyring, notableWork, The Theory of Rate Processes (book, co-authored)]
Generated description
The Theory of Rate Processes is a foundational scientific book that systematically develops the theory of chemical reaction rates and laid the groundwork for modern transition state theory in physical chemistry.
NED2
Entity disambiguation (via description)
gpt-5-mini-2025-08-07
Target entity: The Theory of Rate Processes (book, co-authored) Target entity description: The Theory of Rate Processes is a foundational scientific book that systematically develops the theory of chemical reaction rates and laid the groundwork for modern transition state theory in physical chemistry.
-
A.
Arrhenius equation for temperature dependence of reaction rates
The Arrhenius equation for temperature dependence of reaction rates is a fundamental formula in chemical kinetics that quantitatively relates a reaction’s rate constant to temperature and activation energy, explaining why reactions speed up as temperature increases.
-
B.
Kramers turnover theory
Kramers turnover theory is a foundational concept in chemical physics that describes how reaction rates depend on friction or solvent viscosity, predicting a maximum (turnover) as friction varies.
-
C.
Taube mechanism in electron transfer
The Taube mechanism in electron transfer is a foundational concept in inorganic chemistry that explains how electrons are transferred between metal complexes through ligand-bridged, often inner-sphere, pathways.
-
D.
Fick's first law of diffusion
Fick's first law of diffusion is a fundamental physical law that relates the diffusive flux of particles to the spatial gradient of their concentration, describing how substances move from regions of high to low concentration.
-
E.
Thermodynamics and the Free Energy of Chemical Substances
Thermodynamics and the Free Energy of Chemical Substances is a foundational 1923 textbook by Gilbert N. Lewis and Merle Randall that systematically applied thermodynamic principles to chemical equilibria and free energy, helping to establish modern physical chemistry.
- F. None of above. chosen
Provenance (5 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69c688109c1c8190added9a221292af0 |
completed | March 27, 2026, 1:37 p.m. |
| NER | Named-entity recognition | batch_69c6d22ed30881909e1bfcfb8cf175a2 |
completed | March 27, 2026, 6:53 p.m. |
| NED1 | Entity disambiguation (via context triple) | batch_69c712be7f9c8190b2667fc4c8d5f601 |
completed | March 27, 2026, 11:29 p.m. |
| NEDg | Description generation | batch_69c713842b9c8190ae31eba0bd449968 |
completed | March 27, 2026, 11:32 p.m. |
| NED2 | Entity disambiguation (via description) | batch_69c71444e9ec8190a68531ed29fd9377 |
completed | March 27, 2026, 11:35 p.m. |
Created at: March 27, 2026, 2:12 p.m.