Triple
T6306440
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Gilbert N. Lewis |
E141386
|
entity |
| Predicate | publication |
P80
|
FINISHED |
| Object |
Thermodynamics and the Free Energy of Chemical Substances
Thermodynamics and the Free Energy of Chemical Substances is a foundational 1923 textbook by Gilbert N. Lewis and Merle Randall that systematically applied thermodynamic principles to chemical equilibria and free energy, helping to establish modern physical chemistry.
|
E585210
|
NE FINISHED |
How this triple was built (4 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Thermodynamics and the Free Energy of Chemical Substances | Statement: [Gilbert N. Lewis, publication, Thermodynamics and the Free Energy of Chemical Substances]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Thermodynamics and the Free Energy of Chemical Substances Context triple: [Gilbert N. Lewis, publication, Thermodynamics and the Free Energy of Chemical Substances]
-
A.
On the Equilibrium of Heterogeneous Substances
On the Equilibrium of Heterogeneous Substances is a foundational 1876–1878 treatise in thermodynamics by Josiah Willard Gibbs that introduced key concepts of chemical thermodynamics and phase equilibrium, including the Gibbs free energy.
-
B.
Gibbs free energy
Gibbs free energy is a thermodynamic potential that predicts the spontaneity of processes and the maximum non-expansion work obtainable from a system at constant temperature and pressure.
-
C.
Arrhenius equation for temperature dependence of reaction rates
The Arrhenius equation for temperature dependence of reaction rates is a fundamental formula in chemical kinetics that quantitatively relates a reaction’s rate constant to temperature and activation energy, explaining why reactions speed up as temperature increases.
-
D.
Flory–Huggins solution theory
Flory–Huggins solution theory is a thermodynamic model that describes the mixing behavior and phase separation of polymer solutions by accounting for the size difference between polymer chains and solvent molecules.
-
E.
Carathéodory’s formulation of the second law of thermodynamics
Carathéodory’s formulation of the second law of thermodynamics is a mathematically rigorous restatement of the second law based on the inaccessibility of certain thermodynamic states, providing a foundation for the concept of entropy without relying on cyclic processes or heat engines.
- F. None of above. chosen
- G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg
Description generation
gpt-5.1
Instruction
Generate a one-sentence description of the target entity. You are given a context triple in the form (subject, predicate, object), where the object is the target entity. # Instructions Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. Avoid repeating the information from the triple, unless really essential. # Response Format Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: Thermodynamics and the Free Energy of Chemical Substances Triple: [Gilbert N. Lewis, publication, Thermodynamics and the Free Energy of Chemical Substances]
Generated description
Thermodynamics and the Free Energy of Chemical Substances is a foundational 1923 textbook by Gilbert N. Lewis and Merle Randall that systematically applied thermodynamic principles to chemical equilibria and free energy, helping to establish modern physical chemistry.
NED2
Entity disambiguation (via description)
gpt-5-mini-2025-08-07
Target entity: Thermodynamics and the Free Energy of Chemical Substances Target entity description: Thermodynamics and the Free Energy of Chemical Substances is a foundational 1923 textbook by Gilbert N. Lewis and Merle Randall that systematically applied thermodynamic principles to chemical equilibria and free energy, helping to establish modern physical chemistry.
-
A.
On the Equilibrium of Heterogeneous Substances
On the Equilibrium of Heterogeneous Substances is a foundational 1876–1878 treatise in thermodynamics by Josiah Willard Gibbs that introduced key concepts of chemical thermodynamics and phase equilibrium, including the Gibbs free energy.
-
B.
Gibbs free energy
Gibbs free energy is a thermodynamic potential that predicts the spontaneity of processes and the maximum non-expansion work obtainable from a system at constant temperature and pressure.
-
C.
Arrhenius equation for temperature dependence of reaction rates
The Arrhenius equation for temperature dependence of reaction rates is a fundamental formula in chemical kinetics that quantitatively relates a reaction’s rate constant to temperature and activation energy, explaining why reactions speed up as temperature increases.
-
D.
Flory–Huggins solution theory
Flory–Huggins solution theory is a thermodynamic model that describes the mixing behavior and phase separation of polymer solutions by accounting for the size difference between polymer chains and solvent molecules.
-
E.
Carathéodory’s formulation of the second law of thermodynamics
Carathéodory’s formulation of the second law of thermodynamics is a mathematically rigorous restatement of the second law based on the inaccessibility of certain thermodynamic states, providing a foundation for the concept of entropy without relying on cyclic processes or heat engines.
- F. None of above. chosen
Provenance (5 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69c008d00efc8190a36c05b4b4a3bf4b |
completed | March 22, 2026, 3:20 p.m. |
| NER | Named-entity recognition | batch_69c0647b69f08190bb085f9b700f6453 |
completed | March 22, 2026, 9:51 p.m. |
| NED1 | Entity disambiguation (via context triple) | batch_69c5e44c11f48190a8c3c36172cd8da0 |
completed | March 27, 2026, 1:58 a.m. |
| NEDg | Description generation | batch_69c5edd0f9348190a17d00f402e2cdad |
completed | March 27, 2026, 2:39 a.m. |
| NED2 | Entity disambiguation (via description) | batch_69c5ee31ea6881908e30911ccf447400 |
completed | March 27, 2026, 2:40 a.m. |
Created at: March 22, 2026, 4:28 p.m.