Triple

T5947775
Position Surface form Disambiguated ID Type / Status
Subject Ronald George Wreyford Norrish E132321 entity
Predicate notableWork P4 FINISHED
Object Norrish reaction
The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
E557614 NE FINISHED

How this triple was built (4 steps)

Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.

NER Named-entity recognition gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Norrish reaction | Statement: [Ronald George Wreyford Norrish, notableWork, Norrish reaction]
NED1 Entity disambiguation (via context triple) gpt-5-mini-2025-08-07
Target entity: Norrish reaction
Context triple: [Ronald George Wreyford Norrish, notableWork, Norrish reaction]
  • A. Barton reaction
    The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
  • B. Corey–Kim oxidation
    Corey–Kim oxidation is an organic chemistry reaction that converts primary and secondary alcohols into aldehydes and ketones using N-chlorosuccinimide and dimethyl sulfide under mild conditions.
  • C. Eschenmoser–Claisen rearrangement
    The Eschenmoser–Claisen rearrangement is a variant of the Claisen rearrangement in organic chemistry that converts allylic alcohols and amides into γ,δ-unsaturated carbonyl compounds via a [3,3]-sigmatropic rearrangement.
  • D. Eschenmoser–Tanabe fragmentation
    The Eschenmoser–Tanabe fragmentation is an organic reaction that cleaves certain α,β-epoxy ketones or related substrates to form carbonyl compounds via a synthetically useful carbon–carbon bond fragmentation.
  • E. Robinson annulation reaction
    The Robinson annulation reaction is a classic organic chemistry transformation that forms six-membered rings by combining a Michael addition with an intramolecular aldol condensation, widely used in the synthesis of complex cyclic molecules and natural products.
  • F. None of above. chosen
  • G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg Description generation gpt-5.1
Instruction
Generate a one-sentence description of the target entity. 
You are given a context triple in the form (subject, predicate, object), where the object is the target entity. 
# Instructions
Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. 
Avoid repeating the information from the triple, unless really essential.
# Response Format
Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: Norrish reaction
Triple: [Ronald George Wreyford Norrish, notableWork, Norrish reaction]
Generated description
The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
NED2 Entity disambiguation (via description) gpt-5-mini-2025-08-07
Target entity: Norrish reaction
Target entity description: The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
  • A. Barton reaction
    The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
  • B. Corey–Kim oxidation
    Corey–Kim oxidation is an organic chemistry reaction that converts primary and secondary alcohols into aldehydes and ketones using N-chlorosuccinimide and dimethyl sulfide under mild conditions.
  • C. Eschenmoser–Claisen rearrangement
    The Eschenmoser–Claisen rearrangement is a variant of the Claisen rearrangement in organic chemistry that converts allylic alcohols and amides into γ,δ-unsaturated carbonyl compounds via a [3,3]-sigmatropic rearrangement.
  • D. Eschenmoser–Tanabe fragmentation
    The Eschenmoser–Tanabe fragmentation is an organic reaction that cleaves certain α,β-epoxy ketones or related substrates to form carbonyl compounds via a synthetically useful carbon–carbon bond fragmentation.
  • E. Robinson annulation reaction
    The Robinson annulation reaction is a classic organic chemistry transformation that forms six-membered rings by combining a Michael addition with an intramolecular aldol condensation, widely used in the synthesis of complex cyclic molecules and natural products.
  • F. None of above. chosen

Provenance (5 batches)

The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.

Step Stage Batch ID Status When
creating Elicitation batch_69c00869d3308190af89b2453e0f7546 completed March 22, 2026, 3:19 p.m.
NER Named-entity recognition batch_69c0397c80708190a4778fdb353314b7 completed March 22, 2026, 6:48 p.m.
NED1 Entity disambiguation (via context triple) batch_69c0c08d4f0481908547609bc2736380 completed March 23, 2026, 4:24 a.m.
NEDg Description generation batch_69c0c19665b08190ab3c66b7c6c33f61 completed March 23, 2026, 4:29 a.m.
NED2 Entity disambiguation (via description) batch_69c0c4576824819080ced71df8fdda6c completed March 23, 2026, 4:40 a.m.
Created at: March 22, 2026, 4:01 p.m.