Triple
T5947775
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Ronald George Wreyford Norrish |
E132321
|
entity |
| Predicate | notableWork |
P4
|
FINISHED |
| Object |
Norrish reaction
The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
|
E557614
|
NE FINISHED |
How this triple was built (4 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Norrish reaction | Statement: [Ronald George Wreyford Norrish, notableWork, Norrish reaction]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Norrish reaction Context triple: [Ronald George Wreyford Norrish, notableWork, Norrish reaction]
-
A.
Barton reaction
The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
-
B.
Corey–Kim oxidation
Corey–Kim oxidation is an organic chemistry reaction that converts primary and secondary alcohols into aldehydes and ketones using N-chlorosuccinimide and dimethyl sulfide under mild conditions.
-
C.
Eschenmoser–Claisen rearrangement
The Eschenmoser–Claisen rearrangement is a variant of the Claisen rearrangement in organic chemistry that converts allylic alcohols and amides into γ,δ-unsaturated carbonyl compounds via a [3,3]-sigmatropic rearrangement.
-
D.
Eschenmoser–Tanabe fragmentation
The Eschenmoser–Tanabe fragmentation is an organic reaction that cleaves certain α,β-epoxy ketones or related substrates to form carbonyl compounds via a synthetically useful carbon–carbon bond fragmentation.
-
E.
Robinson annulation reaction
The Robinson annulation reaction is a classic organic chemistry transformation that forms six-membered rings by combining a Michael addition with an intramolecular aldol condensation, widely used in the synthesis of complex cyclic molecules and natural products.
- F. None of above. chosen
- G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg
Description generation
gpt-5.1
Instruction
Generate a one-sentence description of the target entity. You are given a context triple in the form (subject, predicate, object), where the object is the target entity. # Instructions Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. Avoid repeating the information from the triple, unless really essential. # Response Format Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: Norrish reaction Triple: [Ronald George Wreyford Norrish, notableWork, Norrish reaction]
Generated description
The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
NED2
Entity disambiguation (via description)
gpt-5-mini-2025-08-07
Target entity: Norrish reaction Target entity description: The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
-
A.
Barton reaction
The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
-
B.
Corey–Kim oxidation
Corey–Kim oxidation is an organic chemistry reaction that converts primary and secondary alcohols into aldehydes and ketones using N-chlorosuccinimide and dimethyl sulfide under mild conditions.
-
C.
Eschenmoser–Claisen rearrangement
The Eschenmoser–Claisen rearrangement is a variant of the Claisen rearrangement in organic chemistry that converts allylic alcohols and amides into γ,δ-unsaturated carbonyl compounds via a [3,3]-sigmatropic rearrangement.
-
D.
Eschenmoser–Tanabe fragmentation
The Eschenmoser–Tanabe fragmentation is an organic reaction that cleaves certain α,β-epoxy ketones or related substrates to form carbonyl compounds via a synthetically useful carbon–carbon bond fragmentation.
-
E.
Robinson annulation reaction
The Robinson annulation reaction is a classic organic chemistry transformation that forms six-membered rings by combining a Michael addition with an intramolecular aldol condensation, widely used in the synthesis of complex cyclic molecules and natural products.
- F. None of above. chosen
Provenance (5 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69c00869d3308190af89b2453e0f7546 |
completed | March 22, 2026, 3:19 p.m. |
| NER | Named-entity recognition | batch_69c0397c80708190a4778fdb353314b7 |
completed | March 22, 2026, 6:48 p.m. |
| NED1 | Entity disambiguation (via context triple) | batch_69c0c08d4f0481908547609bc2736380 |
completed | March 23, 2026, 4:24 a.m. |
| NEDg | Description generation | batch_69c0c19665b08190ab3c66b7c6c33f61 |
completed | March 23, 2026, 4:29 a.m. |
| NED2 | Entity disambiguation (via description) | batch_69c0c4576824819080ced71df8fdda6c |
completed | March 23, 2026, 4:40 a.m. |
Created at: March 22, 2026, 4:01 p.m.